The powerful runner's selection is a big boost for coach Simon Raiwalui just weeks before the start of the World Cup.
"Habosi has been knocking at the door and finally he has got a chance to showcase his talent," Raiwalui said.
"It's great news that he was cleared of injury and we are looking forward to seeing him and what he has to offer against France."
Centre Semi Radradra, the former Parramatta Eels NRL star, will captain the side, with several other players based in France and able to provide local knowledge, including La Rochelle loose-forward Levani Botia, Bayonne fullback Sireli Maqala and Lyon wing Josua Tuisova.
Iosefo Masi will partner Radradra in the midfield, while Caleb Muntz is given a run at five-eighth and Frank Lomani will wear the No.9 jersey.
The back row of the scrum is made up of Botia, fellow flanker Meli Derenalagi and No.8 Viliame Mata, while Isoa Nasilasila and Te Ahiwaru Cirikidaveta line up at lock.
Hooker Tevita Ikanivere will have props Eroni Mawi and Mesake Doge either side of him.
"This is one of the best opportunities to test ourselves in various areas. The whole team has been working hard for the past few days since arriving at Pornic and we are ready for the match," Raiwalui said.
Fiji are in Pool C at the World Cup along with Wales, Australia, Georgia and Portugal.
FIJI SQUAD V FRANCE
Sireli Maqala, Josua Tuisova, Iosefo Masi, Semi Radradra (capt), Vinaya Habosi, Caleb Muntz, Frank Lomani, Viliame Mata, Levani Botia, Meli Derenalagi, Te Ahiwaru Cirikidaveta, Isoa Nasilasila, Mesake Doge, Tevita Ikanivere, Eroni Mawi.
Replacements: Sam Matavesi, Peni Ravai, Luke Tagi, Temo Mayanavanua, Albert Tuisue, Simione Kuruvoli, Jiuta Wainiqolo, Ilaisa Droasese.
